Isohydric Solutions

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Formulation of the System of Isohydric Solutions

The isohydricity (pH constancy) as the property referred to mixtures of acids or bases, is illustrated on a simple example of the solutions: HL (C0, mol/L) and HL (C mol/L) mixed according to titrimetric mode (pH titration). A new derivation of the Michałowski formula 1 2 0 10 pK C C C    expressing this property is presented, and its applicability for determination of pK1 = – logK1 value is...

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ژورنال

عنوان ژورنال: The Journal of Physical Chemistry

سال: 1900

ISSN: 0092-7325,1541-5740

DOI: 10.1021/j150022a003